Title of article
Synthesis and Spectroscopic Studies of Mixed Catechol-Salicylaldiminate Derivatives of Antimony (III) and Tin (IV)
Author/Authors
AI-Jeboori, M. J. University of Baghdad - College of Education, Ibn AIHaitham - Department of Chemistry, Iraq , Hasan, H. A. University of Baghdad - College of Education, Ibn AIHaitham - Department of Chemistry, Iraq , Abdul Karim, L. K. University of Baghdad - College of Education, Ibn AIHaitham - Department of Chemistry, Iraq
From page
80
To page
90
Abstract
Mixed catechol- salicyladiminenate derivatives of antimony (Ill) and tin (IV) of the general formula M(cate)L]X, [whcre:M= Sb, X= 0; M=Sn, X= Cl; cate=catechol; o=l, L=aniline, n=2, L=mbromo- aniline, n=3, L=p-bromoaniline] were prepared by the reaction of equimolar amount of [(cate)MCln], [where n=l or 2] with Narylsalicylaldimines HOC6H4CH=NC6Hs ~HL1 ), HOC6H4CH= NC6H4 (HL1 ) and p-IIOC6H4CH = NC6H4Br (HL) in methanol as a solvent. These new derivatives were characterised by elemental analysis andspectroscopic methods [(l.R), (U.V-Vis) and (1H, 13C NMR for 11L2)]along with conductivity and melting point measurements. Thesestudies revealed that the geometry about Sb (lll) and Sn (IV) istetrahedral.
Journal title
Ibn Alhaitham Journal For Pure and Applied Science
Journal title
Ibn Alhaitham Journal For Pure and Applied Science
Record number
2601356
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