Title of article :
Synthesis, Spectroscopic and Biological Studies of a New Some Complexes with N-Pyridin-2- Ylmethyl-Benzene-1,2-Diamine
Author/Authors :
Naji, Shaymaa H. University of Baghdad - College of Education For Pure Science(Ibn Al- Haitham) - Department of Chemistry, Iraq , Abdul Karim, Lekaa K. University of Baghdad - College of Education For Pure Science(Ibn Al- Haitham) - Department of Chemistry, Iraq , Mousa, Falih H. University of Baghdad - College of Education For Pure Science(Ibn Al- Haitham) - Department of Chemistry, Iraq
Abstract :
N-Pyridin-2-ylmethyl-benzene-1,2-diamine (L) was prepared from the reaction of ortho amino phenyl thiol with 2 – amino methyl pyridine in mole ratio (1:1) . It was characterized by elemental analysis (C.H.N) , FT-IR , Uv – Vis , ^1H , ^13C-N.M.R . The complexes of the bivalent ions (Co , Ni , Cu ,Pd , Cd , Hg and Pb) and the trivalent (Cr) have been prepared and characterized too . The structural was established by elemental analysis (C.H.N) , FT-IR , Uv – Vis spectra , conductivity measurements , atomic absorption and magnetic susceptibility . The complexes showed characteristic behavior of octahedral geometry around the metal ions and the (N,N,N) ligand coordinated in tridentat mode except with Pd complexes showed sequare planer . α ,Kf,εmax for the complexes were estimated too. β for Co – complex was calculated . The study of biological activity of the ligand (L) and its complexes showed various activity toward staphylococcus aureus and E.coli.
Keywords :
Synthesis , Phenyl diamine , Complexes , Biological study , Bivalent ions
Journal title :
Ibn Alhaitham Journal For Pure and Applied Science
Journal title :
Ibn Alhaitham Journal For Pure and Applied Science