Title of article :
Crystal structure of the coordination compound of triiodidomethyltin(IV) with 2,2′-bipyridine, MeSnI3·bipy
Author/Authors :
Reuter, Hans Institute of Chemistry of New Materials - University of Osnabrueck, Germany , Reichelt, Martin Institute of Chemistry of New Materials - University of Osnabrueck, Germany
Abstract :
The title complex is one of the few structurally characterized coordination compounds of an organotin(IV) trihalide with 2,2′-biypridine. Its distorted octahedral geometry shows a meridional arrangement of the I atoms and the methyl group is in-plane with the five-membered chelate ring. Directional intermolecular interactions are restricted to weak I⋯H van der Waals contacts.
Keywords :
coordination compound , 2,20 -bipyridine; , methyltin(IV) triiode , crystal structure
Journal title :
Acta Crystallographica Section E: Crystallographic Communications