• Title of article

    Crystal structure of poly[di­aqua­(μ-2-carb­oxy­acetato-κ3O,O′:O′′)(2-carb­oxy­acetato-κO)di-μ-chlorido-dicobalt(II)]

  • Author/Authors

    Bouaoud,Yasmina Unite´ de Recherche de Chimie de l’Environnement et Mole´culaire Structurale (CHEMS) - Universite´ Constantine 1, Algeria , Setifi,Zouaoui Unite´ de Recherche de Chimie de l’Environnement et Mole´culaire Structurale (CHEMS) - Universite´ Constantine 1, Algeria , Buvailo, Andrii National Taras Shevchenko University of Kyiv - Department of Chemistry, Ukraine, , Potaskalov, Vadim A. Department of General and Inorganic Chemistry - National Technical University of Ukraine, Ukraine , Merazig, Hocine Unite´ de Recherche de Chimie de l’Environnement et Mole´culaire Structurale (CHEMS) - Universite´ Constantine 1, Algeria , Denes,Georges f Laboratory of Solid State Chemistry and Mo¨ssbauer Spectroscopy - Laboratories for Inorganic Materials - Department of Chemistry and Biochemistry - Concordia University, Canada

  • Pages
    8
  • From page
    1
  • To page
    8
  • Abstract
    The asymmetric unit of the title polymer, [Co2(C3H3O4)2Cl2(H2O)2]n, comprises one CoII atom, one water molecule, one singly deprotonated malonic acid molecule (HMal; systematic name 2-carboxyacetate) and one Cl anion. The CoII atom is octahedrally coordinated by the O atom of a water molecule, by one terminally bound carboxylate O atom of an HMal anion and by two O atoms of a chelating HMal anion, as well as by two Cl anions. The Cl anions bridge two CoII atoms, forming a centrosymmetric Co2Cl2 core. Each malonate ligand is involved in the formation of six-membered chelate rings involving one CoII atom of the dinuclear unit and at the same time is coordinating to another CoII atom of a neighbouring dinuclear unit in a bridging mode. The combination of chelating and bridging coordination modes leads to the formation of a twodimensional coordination polymer extending parallel to (001). Within a layer, O—HwaterCl and O—HwaterO hydrogen bonds are present. Adjacent layers are linked through O—HO C hydrogen bonds involving the carboxylic acid OH and carbonyl groups.
  • Keywords
    coordination polymer , crystal structure , malonate , cobalt
  • Journal title
    Acta Crystallographica Section E: Crystallographic Communications
  • Serial Year
    2016
  • Full Text URL
    journals.iucr.org/e/issues/2016/01/00/wm5235/wm5235.pdf
  • Record number

    2614361

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=2614361