Author/Authors :
Triantis, Charalampos Institute of Nuclear and Radiological Sciences and Technology - Energy and Safety - National Centre for Scientific Research "Demokritos", Greece , Shegani, Antonio Institute of Nuclear and Radiological Sciences and Technology - Energy and Safety - National Centre for Scientific Research "Demokritos", Greece , Kiritsis, Christos Institute of Nuclear and Radiological Sciences and Technology - Energy and Safety - National Centre for Scientific Research "Demokritos", Greece , Raptopoulou, Catherine P. Institute of Nanoscience and Nanotechnology - National Centre for Scientific Research "Demokritos", Greece , Psycharis,Vassilis Institute of Nanoscience and Nanotechnology - National Centre for Scientific Research "Demokritos", Greece , Pelecanou,Maria Institute of Nanoscience and Nanotechnology - National Centre for Scientific Research "Demokritos", Greece , Pirmettis, Ioannis Institute of Nuclear and Radiological Sciences and Technology - Energy and Safety - National Centre for Scientific Research "Demokritos", Greece , Papadopoulos, Minas Institute of Nuclear and Radiological Sciences and Technology - Energy and Safety - National Centre for Scientific Research "Demokritos", Greece
Abstract :
In the title compound, [Re(C10H6NO2)(CO)3{As(C6H5)3}], the coordination environment of ReI is that of a distorted octahedron. Three coordination sites are occupied by three carbonyl groups in a facial arrangement and the remaining three sites by triphenylarsane and deprotonated quinaldic acid in As-mono- and N,O-bidentate fashions, respectively. In the crystal, the complexes are linked through weak C—H⋯O hydrogen bonds, forming a three-dimensional network. It worth noting that, as far as we know, this complex is the first ReI triphenylarsane tricarbonyl compound to be reported.
Keywords :
crystal structure , trans influence , rhenium(I) tricarbonyl complex , rhenium(I) triphenylarsane and quinaldic acid complex
