• Title of article

    Crystal structure of fac-tricarbon­yl(quinoline-2-carboxyl­ato-κ2N,O)(tri­phenyl­arsane-κAs)rhenium(I)

  • Author/Authors

    Triantis, Charalampos Institute of Nuclear and Radiological Sciences and Technology - Energy and Safety - National Centre for Scientific Research "Demokritos", Greece , Shegani, Antonio Institute of Nuclear and Radiological Sciences and Technology - Energy and Safety - National Centre for Scientific Research "Demokritos", Greece , Kiritsis, Christos Institute of Nuclear and Radiological Sciences and Technology - Energy and Safety - National Centre for Scientific Research "Demokritos", Greece , Raptopoulou, Catherine P. Institute of Nanoscience and Nanotechnology - National Centre for Scientific Research "Demokritos", Greece , Psycharis,Vassilis Institute of Nanoscience and Nanotechnology - National Centre for Scientific Research "Demokritos", Greece , Pelecanou,Maria Institute of Nanoscience and Nanotechnology - National Centre for Scientific Research "Demokritos", Greece , Pirmettis, Ioannis Institute of Nuclear and Radiological Sciences and Technology - Energy and Safety - National Centre for Scientific Research "Demokritos", Greece , Papadopoulos, Minas Institute of Nuclear and Radiological Sciences and Technology - Energy and Safety - National Centre for Scientific Research "Demokritos", Greece

  • Pages
    9
  • From page
    1
  • To page
    9
  • Abstract
    In the title compound, [Re(C10H6NO2)(CO)3{As(C6H5)3}], the coordination environment of ReI is that of a distorted octa­hedron. Three coordination sites are occupied by three carbonyl groups in a facial arrangement and the remaining three sites by tri­phenyl­arsane and deprotonated quinaldic acid in As-mono- and N,O-bidentate fashions, respectively. In the crystal, the complexes are linked through weak C—H⋯O hydrogen bonds, forming a three-dimensional network. It worth noting that, as far as we know, this complex is the first ReI tri­phenyl­arsane tricarbonyl compound to be reported.
  • Keywords
    crystal structure , trans influence , rhenium(I) tricarbonyl complex , rhenium(I) triphenylarsane and quinaldic acid complex
  • Journal title
    Acta Crystallographica Section E: Crystallographic Communications
  • Serial Year
    2016
  • Record number

    2614561