Title of article
Crystal structure of an organic–inorganic supramolecular salt based on a 4,4′-methylenebis(3,5-dimethyl-1H-pyrazol-2-ium) cation and a β-octamolybdate anion
Author/Authors
Amarante,Tatiana R. Department of Chemistry - CICECO – Aveiro Institute of Materials - University of Aveiro, Portugal , Gonc alves, Isabel S. Department of Chemistry - CICECO – Aveiro Institute of Materials - University of Aveiro, Portugal , Almeida Paz, Filipe A. Department of Chemistry - CICECO – Aveiro Institute of Materials - University of Aveiro, Portugal
Pages
11
From page
1
To page
11
Abstract
The asymmetric unit of the title compound, bis[4,40
-methylenebis(3,5-dimethyl1H-pyrazol-2-ium)] -octamolybdate, (C11H18N4)2[Mo8O26] or
(H4mbdpz)2[Mo8O26], is composed of an H4mbdpz2+ cation and half of the
-octamolybdate anion which is completed by inversion symmetry. The organic
molecular units are engaged in a series of N—HO hydrogen bonds with
neighbouring anions, with NO distances and N—HO angles in the ranges
2.730 (2)–2.941 (2) A˚ and 122–166, respectively. These interactions lead to the
formation of a supramolecular two-dimensional network parallel to the (010)
plane
Keywords
hydrogen-bonding network , octamolybdate anion , 4,40 -methylenebis(3,5-dimethyl-1H-pyrazol-2-ium) cation , crystal structure
Journal title
Acta Crystallographica Section E: Crystallographic Communications
Serial Year
2016
Record number
2614566
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