Title of article :
Crystal structure of (n-butyl)[2-(2,6-dimethoxyphenyl)-6-methylphenyl](2-methoxyphenyl)phosphonium chloride monohydrate
Author/Authors :
Feng, Ge Department of Chemistry - the University of Chicago, USA , Filatov, Alexander S. Department of Chemistry - the University of Chicago, USA , Jordan, Richard F. Department of Chemistry - the University of Chicago, USA
Abstract :
The title hydrated salt, C26H32O3P+·Cl−·H2O, contains four different substituents (H, alkyl, aryl, and biaryl) on the P atom. The P—H hydrogen atom of the phosphonium ion was located in a difference Fourier map and refined without imposing additional restraints. In the crystal, the Cl− ions and water molecules are linked by pairs of Owater—H⋯Cl− hydrogen bonds and further linked to the phosphonium cation by P—H+⋯Cl− and CAr/OMe—H⋯Owater hydrogen bonds to form an infinite one-dimensional chain along the [010] direction.
Keywords :
hydrogen bonding , crystal structure , phosphonium salt
Journal title :
Acta Crystallographica Section E: Crystallographic Communications