Title of article
Crystal structure of fac-tricarbonyl(cyclohexyl isocyanide-κC)(quinoline-2-carboxylato-κ2N,O)rhenium(I)
Author/Authors
Triantis, Charalampos Institute of Nuclear and Radiological Sciences and Technology - Energy and Safety - National Centre for Scientific Research `Demokritos', Greece , Shegani, Antonio Institute of Nuclear and Radiological Sciences and Technology - Energy and Safety - National Centre for Scientific Research `Demokritos', Greece , Raptopoulou, Catherine Institute of Nanoscience and Nanotechnology - National Centre for Scientific Research ‘Demokritos’, Greece , Psycharis,Vassilis Institute of Nanoscience and Nanotechnology - National Centre for Scientific Research ‘Demokritos’, Greece , Kiritsis, Christos Institute of Nuclear and Radiological Sciences and Technology - Energy and Safety - National Centre for Scientific Research `Demokritos', Greece , Pelecanou, Maria Institute of Biosciences & Applications - National Centre for Scientific Research ‘Demokritos’, Greece , Pirmettisa, Ioannis Institute of Nuclear and Radiological Sciences and Technology - Energy and Safety - National Centre for Scientific Research `Demokritos', Greece , Papadopoulos, Minas Institute of Nuclear and Radiological Sciences and Technology - Energy and Safety - National Centre for Scientific Research `Demokritos', Greece
Pages
10
From page
1
To page
10
Abstract
In the title compound, [Re(C10H6NO2)(C7H11N)(CO)3], the ReI atom is coordinated by three carbonyl ligands in a facial arrangement and by the N, O and C atoms from a chelating quinaldate anion and a monodentate isocyanide ligand, respectively. The resultant C4NO coordination sphere is distorted octahedral. A lengthening of the axial Re—CO bond trans to the isocyanide ligand is indicative of the trans effect. Individual complexes are stacked into rods parallel to [001] through displaced π–π interactions. Weak C—H⋯O hydrogen-bonding interactions between the rods lead to the formation of layers parallel to (010). These layers are stacked along [010] by C—H⋯H—C van der Waals contacts.
Keywords
rhenium(I) tricarbonyl complex , rhenium(I) cyclohexyl isocyanide and quinaldic acid complex , crystal structure , structural trans effect , Hirshfeld surface analysis
Journal title
Acta Crystallographica Section E: Crystallographic Communications
Serial Year
2016
Record number
2617492
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