Title of article :
Crystal structure of 5′′-benzyl­­idene-1′-methyl-4′-phenyl­tri­spiro­[ace­naphthyl­ene-1,2′-pyrrolidine-3′,1′′-cyclo­hexane-3′′,2′′′-[1,3]dioxane]-2,6′′-dione
Author/Authors :
Chandralekha, Kuppan Research Department of Physics - S. D. N. B. Vaishnav College for Women, India , Gavaskar, Deivasigamani Department of Organic Chemistry - University of Madras - Guindy Campus, India , Sureshbabu, Adukamparai Rajukrishnan Department of Organic Chemistry - University of Madras - Guindy Campus, India , Lakshmi, Srinivasakannan Research Department of Physics - S. D. N. B. Vaishnav College for Women, India
Pages :
12
From page :
1
To page :
12
Abstract :
In the title compound, C36H31NO4, two spiro links connect the methyl-substituted pyrrolidine ring to the ace­naphthyl­ene and cyclo­hexa­none rings. The cyclo­hexa­none ring is further connected to the dioxalane ring by a third spiro junction. The five-membered ring of the ace­naphthylen-1-one ring system adopts a flattened envelope conformation with the ketonic C atom as flap, whereas the dioxalane and pyrrolidine rings each have a twist conformation. The cyclo­hexa­none ring assumes a boat conformation. Three intra­molecular C—H⋯O hydrogen bonds involving both ketonic O atoms as acceptors are present. In the crystal, C—H⋯O hydrogen bonds connect centrosymmetrically related mol­ecule into chains parallel to the b axis, forming rings of R22(10)and R22(8) graph-set motifs.
Keywords :
dioxalane , crystal structure , spiro­cyclo­hexa­nones , ace­naphthyl­ene , tris­piropyrrolidines
Journal title :
Acta Crystallographica Section E: Crystallographic Communications
Serial Year :
2016
Full Text URL :
Record number :
2617501
Link To Document :
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