Title of article :
Crystal structure of bis­­{μ2-3-(pyridin-2-yl)-5-[(1,2,4-triazol-1-yl)meth­yl]-1,2,4-triazolato}bis­­[aqua­nitrato­copper(II)] dihydrate
Author/Authors :
Doroschuk, Roman Department of Inorganic Chemistry - Taras Shevchenko National University of Kyiv, Kyiv
Pages :
8
From page :
1
To page :
8
Abstract :
The structure of the dinuclear title complex, [Cu2(C10H8N7)2(NO3)2(H2O)2]·2H2O, consists of centrosymmetric dimeric units with a copper–copper separation of 4.0408 (3) Å. The CuII ions in the dimer display a distorted octa­hedral coordination geometry and are bridged by two triazole rings, forming an approximately planar Cu2N4 core (r.m.s. deviation = 0.049 Å). In the crystal, O—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds and π–π inter­actions link the mol­ecules into a three-dimensional network.
Keywords :
hydrogen bonds. , dinuclear copper complex , dinuclear copper complex , crystal structure , 1,2,4-triazole
Journal title :
Acta Crystallographica Section E: Crystallographic Communications
Serial Year :
2016
Full Text URL :
Record number :
2617724
Link To Document :
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