• Title of article

    Crystal structure of 3-benzamido-1-(4-nitro­benz­yl)quinolinium tri­fluoro­methane­sulfonate

  • Author/Authors

    Nicolas-Gomez, Mariana Centro Conjunto de Investigacion en Quimica Sustentable UAEM–UNAM, Instituto de Quimica - Universidad Nacional Autonoma de Mexico - Carretera Toluca-Atlacomulco, Mexico , Bazany-Rodrı´guez, a Iva´n J. Centro Conjunto de Investigacion en Quimica Sustentable UAEM–UNAM, Instituto de Quimica - Universidad Nacional Autonoma de Mexico - Carretera Toluca-Atlacomulco, Mexico , ndez-Ortegab, Simo´n Herna´ Laboratorio de Rayos-X - Instituto de Quimica, UNAM - Circuito Exterior - Ciudad Universitaria Deleg. Mexico , Plata-Vargas, Eduardo Centro Conjunto de Investigacion en Quimica Sustentable UAEM–UNAM, Instituto de Quimica - Universidad Nacional Autonoma de Mexico - Carretera Toluca-Atlacomulco, Mexico , ´ndez-Ortegab, Simo´n Herna Centro Conjunto de Investigacion en Quimica Sustentable UAEM–UNAM, Instituto de Quimica - Universidad Nacional Autonoma de Mexico - Carretera Toluca-Atlacomulco, Mexico

  • Pages
    13
  • From page
    1
  • To page
    13
  • Abstract
    In the title compound, C23H18N3O3+·CF3SO3−, the asymmetric unit contains two crystallographically independent organic cations with similar conformations. Each cation shows a moderate distortion between the planes of the amide groups and the quinolinium rings with dihedral angles of 14.90 (2) and 31.66 (2)°. The quinolinium and phenyl rings are slightly twisted with respect to each other at dihedral angles of 6.99 (4) and 8.54 (4)°. The tri­fluoro­methane­sulfonate anions are linked to the organic cations via N—H⋯O hydrogen-bonding inter­actions involving the NH amide groups. In the crystal, the organic cations are linked by weak C—H⋯O(nitro group) inter­actions into supramol­ecular chains propagating along the b-axis direction.
  • Keywords
    p-nitro­benzyl­quinolinium , tri­fluoro­methane­sulfonate salt , benzamide , benzamide , crystal structure
  • Journal title
    Acta Crystallographica Section E: Crystallographic Communications
  • Serial Year
    2016
  • Full Text URL
    journals.iucr.org/e/issues/2016/05/00/hg5469/hg5469.pdf
  • Record number

    2617933

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=2617933