Title of article
Crystal structure of bis(acetophenone 4-benzoylthiosemicarbazonato-κ2N1,S)nickel(II)
Author/Authors
Karim Kadir,Faraidoon Department of Chemistry - Faculty of Science - Universiti Teknologi Malaysia, Malaysia , Shamsuddin, Mustaffa Department of Chemistry - Faculty of Science - Universiti Teknologi Malaysia, Malaysia , Mustaqim Rosli, Mohd Department of Chemistry - School of Science - Faculty of Science & Education - University of Sulaimani, Kurdistan Region, Iraq
Pages
11
From page
1
To page
11
Abstract
In the asymmetric unit of the title complex, [Ni(C16H14N3OS)2], the nickel ion is tetracoordinated in a distorted square-planar geometry by two independent molecules of the ligand which act as mononegative bidentate N,S-donors and form two five-membered chelate rings. The ligands are in trans (E) conformations with respect to the C=N bonds. The close approach of hydrogen atoms to the Ni2+ atom suggests anagostic interactions (Ni⋯H—C) are present. The crystal structure is built up by a network of two C—H⋯O interactions. One of the interactions forms inversion dimers and the other links the molecules into infinite chains parallel to [100]. In addition, a weak C—H⋯π interaction is also present.
Keywords
crystal structure , C—H⋯O interactions , anagostic interactions , anagostic interactions , nickel(II) , thiosemicarbazone
Journal title
Acta Crystallographica Section E: Crystallographic Communications
Serial Year
2016
Record number
2617937
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