Title of article
Crystal structure of (acetato-κO)(ethanol-κO)[(9S,17S,21S,29S)-9,17,21,29-tetrahydroxy-18,30-dioxaoctacyclo[18.10.0.02,7.08,19.09,17.011,16.021,29.023,28]triaconta-1,3,5,7,11(16),12,14,19,23(28),24,26-undecaene-10,22-dione-κ3O18,O21,O22]caesium ethanol monosolvate
Author/Authors
Bengiat, Ravell Institute of Chemistry - The Hebrew University of Jerusalem, Israel , Gil, Maayan Institute of Chemistry - The Hebrew University of Jerusalem, Israel , Klein, Asne Institute of Chemistry - The Hebrew University of Jerusalem, Israel , Bogoslavsky, Benny Institute of Chemistry - The Hebrew University of Jerusalem, Israel , Cohen, Shmuel Institute of Chemistry - The Hebrew University of Jerusalem, Israel , Yardeni, Guy Department of Chemistry - Nuclear Research Centre Negev, Israel , Zilbermann, Israel Department of Chemistry - Nuclear Research Centre Negev, Israel , Almoga, Joseph Institute of Chemistry - The Hebrew University of Jerusalem, Israel
Pages
12
From page
1
To page
12
Abstract
The title compound, [Cs(CH3COO)(C28H16O8)(C2H5OH)]·C2H5OH, is the product of the complexation between one vasarene analogue [1], bis ninhydrin naphthalene-1,3-diol and CsF, where the F− ion has reacted with residual acetic acid (AcOH), to form a [1]·CsOAc complex. The intermolecular interactions with the multiple oxygen-containing functional groups of the ligand, as well as O—H⋯O hydrogen bonds involving the ethanol solvent molecules, stabilize the complex, forming a chain along [100]. Additional parallel-displaced π–π stacking, with an interplanar distance of 3.669 (1) Å, connect several unit cells in a three-dimensional supramolecular structure, though, the larger size of AcO− (1.60 Å) compared to F− (1.33 Å) prevents the tight packing that was once achieved with other vasarene complexes of CsF.
Keywords
supramolecular complex , ninhydrin , ion-pair recognition , vasarenes , crystal structure
Journal title
Acta Crystallographica Section E: Crystallographic Communications
Serial Year
2016
Record number
2618267
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