Title of article :
Crystal structure of dimethyl 3,4,5,6-tetraphenylcyclohexa-3,5-diene-1,2-dicarboxylate
Author/Authors :
Greenberga, Fred H. Chemistry Department - SUNY Buffalo State, USA , Nazarenkoa, Alexander Y. Chemistry Department - SUNY Buffalo State, USA
Abstract :
In the title compound, C34H28O4, the cyclohexadiene ring has a screw-boat conformation with a torsion angle between the double bonds being on average ca 15° [15.2 (3) and −15.3 (3) in the two independent molecules]. All four phenyl rings in both molecules are arranged in a propeller-like conformation. The two molecules exhibit S,R- and R,S- chirality, respectively, and are connected via C—H⋯O intermolecular interactions. In turn, these weakly bound dimers form the molecular crystal.
Keywords :
crystal structure , conformation. , 1,3-cyclohexadiene , crystal structure
Journal title :
Acta Crystallographica Section E: Crystallographic Communications