Title of article
Crystal structure of dimethyl 3,4,5,6-tetraphenylcyclohexa-3,5-diene-1,2-dicarboxylate
Author/Authors
Greenberga, Fred H. Chemistry Department - SUNY Buffalo State, USA , Nazarenkoa, Alexander Y. Chemistry Department - SUNY Buffalo State, USA
Pages
16
From page
1
To page
16
Abstract
In the title compound, C34H28O4, the cyclohexadiene ring has a screw-boat conformation with a torsion angle between the double bonds being on average ca 15° [15.2 (3) and −15.3 (3) in the two independent molecules]. All four phenyl rings in both molecules are arranged in a propeller-like conformation. The two molecules exhibit S,R- and R,S- chirality, respectively, and are connected via C—H⋯O intermolecular interactions. In turn, these weakly bound dimers form the molecular crystal.
Keywords
crystal structure , conformation. , 1,3-cyclohexadiene , crystal structure
Journal title
Acta Crystallographica Section E: Crystallographic Communications
Serial Year
2016
Record number
2618356
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