Crystal structure and Hirshfeld-surface analysis of (benzene­carbo­thio­amide-κS)bromido­bis­­(tri­phenylphosphane-κP)silver(I)

The title complex, [AgBr(C7H7NS)(C18H15P)2], was obtained from the reaction of silver(I) bromide with benzene­carbo­thio­amide (C7H7NS) and tri­phenyl­phosphane (C18H15P) in the mixed solvent of aceto­nitrile and ethanol. The mononuclear complex exhibits a distorted tetra­hedral coordination geometry about the metal atom, arising from one S atom of a benzene­carbo­thio­amide ligand, two P atoms of two tri­phenyl­phosphane mol­ecules and one bromide ion. An intra­molecular N—H⋯Br hydrogen bond is observed and in the crystal structure, inversion dimers linked by pairs of N—H⋯Br and C—H⋯Br hydrogen bonds are observed. In addition, C—H⋯π inter­actions occur, leading to [101] chains. Hirshfeld-surface analyses are presented and discussed.