Title of article
Crystal structure and Hirshfeld-surface analysis of (benzenecarbothioamide-κS)bromidobis(triphenylphosphane-κP)silver(I)
Author/Authors
Ruangwut,Wattana Department of Chemistry and Center of Excellence for Innovation in Chemistry - Faculty of Science - Prince of Songkla University,Thailand , Saithong, Saowanit Department of Chemistry and Center of Excellence for Innovation in Chemistry - Faculty of Science - Prince of Songkla University,Thailand , Pakawatchai, Chaveng Department of Chemistry and Center of Excellence for Innovation in Chemistry - Faculty of Science - Prince of Songkla University,Thailand
Pages
12
From page
1
To page
12
Abstract
The title complex, [AgBr(C7H7NS)(C18H15P)2], was obtained from the reaction of silver(I) bromide with benzenecarbothioamide (C7H7NS) and triphenylphosphane (C18H15P) in the mixed solvent of acetonitrile and ethanol. The mononuclear complex exhibits a distorted tetrahedral coordination geometry about the metal atom, arising from one S atom of a benzenecarbothioamide ligand, two P atoms of two triphenylphosphane molecules and one bromide ion. An intramolecular N—H⋯Br hydrogen bond is observed and in the crystal structure, inversion dimers linked by pairs of N—H⋯Br and C—H⋯Br hydrogen bonds are observed. In addition, C—H⋯π interactions occur, leading to [101] chains. Hirshfeld-surface analyses are presented and discussed.
Keywords
triphenylphosphane , crystal structure , benzenecarbothioamide , AgI complex , hydrogen bonding , supramolecular interaction , Hirshfeld surface
Journal title
Acta Crystallographica Section E: Crystallographic Communications
Serial Year
2016
Record number
2618365
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