Title of article :
Synthesis and crystal structure of [2,7,12-trimethyl-3,7,11,17-tetraazabicyclo[11.3.1]heptadeca-1(17),13,15-triene-κ4N]copper(II) bis(perchlorate)
Author/Authors :
Hilvano, Edward Gabrielle V. Department of Physical Sciences and Mathematics - College of Arts and Sciences - University of the Philippines, Philippines , Yang, Guang department of Chemistry, Tufts University, Medford, USA , Emnacen, Inno A. Department of Physical Sciences and Mathematics - College of Arts and Sciences - University of the Philippines, Philippines , Rybak-Akimova,Elena V. department of Chemistry, Tufts University, Medford, USA , Billones, Junie B. Department of Physical Sciences and Mathematics - College of Arts and Sciences - University of the Philippines, Philippines , Carrillo, Maria Constancia O. Department of Physical Sciences and Mathematics - College of Arts and Sciences - University of the Philippines, Philippines , Noll, Bruce C. Bruker AXS Inc. - 5465 E. Cheryl Parkway - Madison, WI 53711, USA , Organoa, Voltaire G. Department of Physical Sciences and Mathematics - College of Arts and Sciences - University of the Philippines, Philippines
Abstract :
The title copper(II) complex of a pyridine-containing macrocycle (PyMAC), [Cu(C16H28N4)](ClO4)2, has been prepared. The crystal structure reveals the CuII atom to be octahedrally coordinated by a tetradentate aminopyridine macrocyclic ligand surrounding the metal cation in a square-planar geometry. Two weakly bound perchlorate counter-ions occupy the axial sites above and below the macrocyclic plane. The crystal studied was refined as a two-component pseudo-merohedral twin; the refined fractional contribution of the minor component is 38.77 (8)%
