Title of article
Crystal structure of bis(N,N,N′,N′-tetramethylguanidinium) tetrachloridocuprate(II)
Author/Authors
Ndiaye, Mamadou Laboratoire des Produits Naturels - Département de Chimie - Faculté des Sciences et Techniques - Université Cheikh Anta Diop, Dakar, Senegal , Samb, Abdoulaye Laboratoire des Produits Naturels - Département de Chimie - Faculté des Sciences et Techniques - Université Cheikh Anta Diop, Dakar, Senegal , Maris, Thierry Laboratoire de Chimie Minérale et Analytique - Département de Chimie - Faculté des Sciences et Techniques - Université Cheikh Anta Diop, Dakar, Senegal
Pages
7
From page
1
To page
7
Abstract
In the structure of the title salt, (C5H14N3)2[CuCl4], the CuII atom in the anion lies on a twofold rotation axis. The tetrachloridocuprate(II) anion adopts a flattened tetrahedral coordination environment and interacts electrostatically with the tetramethylguanidinium cation. The crystal packing is additionally consolidated through N—H⋯Cl and C—H⋯Cl hydrogen bonds, resulting in a three-dimensional network structure.
Keywords
τ4 index , tetramethylguanidinium , crystal structure , organic–inorganic hybrid salt
Journal title
Acta Crystallographica Section E: Crystallographic Communications
Serial Year
2016
Record number
2618496
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