Title of article :
Crystal structure of 9-(dibromomethyl)-1,1-difluoro-3,7-dimethyl-1H-[1,3,5,2]oxadiazaborinino[3,4-a][1,8]naphthyridin-11-ium-1-uide
Author/Authors :
Wang, Bang Zhong College of Chemistry and Chemical Engineering - Yunnan Normal University, People's Republic of China , Zhou, Jun Ping College of Chemistry and Chemical Engineering - Yunnan Normal University, People's Republic of China , Zhou, Yong College of Chemistry and Chemical Engineering - Yunnan Normal University, People's Republic of China , Luo, Jian Song College of Chemistry and Chemical Engineering - Yunnan Normal University, People's Republic of China , Chi, Shao Ming College of Chemistry and Chemical Engineering - Yunnan Normal University, People's Republic of China
Abstract :
The molecule of the title 1,8-naphthyridine-BF2 derivative, C12H10BBr2F2N3O, is located on a mirror plane running parallel to the entire ring system and the attached methyl C atoms. Individual molecules are stacked along the b-axis direction. The cohesion in the crystal structure is accomplished by C—H⋯F hydrogen bonds and additional off-set π–π interactions [centroid-to-centroid distance = 3.6392 (9) Å, slippage 0.472 Å], leading to the formation of a three-dimensional supramolecular network.
Keywords :
crystal structure , hydrogen bonding , 1,8-naphthyridine BF2 complex
Journal title :
Acta Crystallographica Section E: Crystallographic Communications
