Author/Authors :
Rayes, Ali Unité de Recherche - Catalyse et Matériaux pour l'Environnement et les Procédés, URCMEP, (UR11ES85 - Faculté des Sciences de Gabès - Campus Universitaire, Tunisia , Rayes, Ali Unité de Recherche - Catalyse et Matériaux pour l'Environnement et les Procédés, URCMEP, (UR11ES85 - Faculté des Sciences de Gabès - Campus Universitaire, Tunisia , Rhouma, Najla Mahbouli Laboratoire des Sciences des Matériaux et d'Environnement - Faculté des Sciences - Université de Sfax,Tunisia , Mezzadri, Francesco Dipartimento di Chimica - Universitá di Parma, Italy , Calestani, Gianluca Dipartimento di Chimica - Universitá di Parma, Italy
Abstract :
The asymmetric unit of the title salt, [p-FC6H4CH2NH3]+·H2PO4−, contains one 4-fluorobenzylammonium cation and one dihydrogen phosphate anion. In the crystal, the H2PO4− anions are linked by O—H⋯O hydrogen bonds to build corrugated layers extending parallel to the ab plane. The FC6H4CH2NH3+ cations lie between these anionic layers to maximize the electrostatic interactions and are linked to the H2PO4− anions through N—H⋯O hydrogen bonds, forming a three-dimensional supramolecular network. Two hydrogen atoms belonging to the dihydrogen phosphate anion are statistically occupied due to disorder along the OH⋯HO direction.
