Title of article :
Crystal structure of (E)-9-({[4-(di­ethyl­amino)­phen­yl]imino}­meth­yl)-2,3,6,7-tetra­hydro-1H,5H-pyrido[3,2,1-ij]quinolin-8-ol
Author/Authors :
Haque Faizia, Md. Serajul Department of Chemistry - College of Science - Sultan Qaboos University, Oman , Ahmad, Musheer Department of Applied Chemistry - Aligarh Muslim University, India , Kapshuk, Anatoly A. Department of Chemistry - Taras Shevchenko National University of Kyiv, Ukraine , Golenya, Irina A. Department of Chemistry - Taras Shevchenko National University of Kyiv, Ukraine
Pages :
11
From page :
1
To page :
11
Abstract :
The title compound, C23H29N3O, was synthesized from the condensation reaction of 8-hy­droxy­julolidine-9-carbaldehyde and N,N-diethyl-p-phenyl­enedi­amine. The hy­droxy group forms a intra­molecular hydrogen bond to the imine N atom and generates an S(6) ring motif. The conformation about the C=N bond is E, and the aromatic ring of the julolidine moiety is inclined to the benzene ring by 3.74 (14)°. One of the fused non-aromatic rings of the julolidine moiety adopts an envelope conformation and the other has a screw-boat conformation. In the crystal, mol­ecules are linked by C—H⋯π inter­actions involving the aromatic julolidine ring, forming slabs parallel to the bc plane. The tricyclic fragment of the julolidine ring and the azomethine C=N bond are disordered over two sets of sites with a refined occupancy ratio of 0.773 (3):0.227 (3).
Keywords :
C—H⋯π inter­actions , crystal structure , hydrogen bonding , Schiff base , N,N-diethyl-p-phenyl­enedi­amine , 8-hy­droxy­julolidine-9-carboxaldehyde , julolidine
Journal title :
Acta Crystallographica Section E: Crystallographic Communications
Serial Year :
2017
Full Text URL :
Record number :
2620513
Link To Document :
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