• Title of article

    Crystal structure of tris­[(4,7,13,16,21,24-hexa­oxa-1,10-di­aza­bi­cyclo­[8.8.8]hexa­cosane-κ8N2,O6)rubidium] rubidium nona­stannide

  • Author/Authors

    Klein, Wilhelm Technische Universität München - Department of Chemistry, Germany , He, Haiyan Technische Universität München - Department of Chemistry, Germany , Fässler, Thomas F. Technische Universität München - Department of Chemistry, Germany

  • Pages
    22
  • From page
    1
  • To page
    22
  • Abstract
    The crystal structure of the title compound, [Rb(C18H36N2O6)]3RbSn9, consists of deltahedral [Sn9]4– cluster anions, Rb+ cations and cryptand mol­ecules, which partially sequester the cations. Those cations, which are not coordinated by cryptand mol­ecules, are neighboured directly to the [Sn9]4– clusters and inter­connect them to form ∞1[RbSn9]3– chains. These chains extend parallel to [001] and are arranged in a pseudo-hexa­gonal rod packing, separated by the Rb-cryptand complex cations.
  • Keywords
    tin , isotypism , crystal structure , stannides , Zintl anions , cage compounds
  • Journal title
    Acta Crystallographica Section E: Crystallographic Communications
  • Serial Year
    2017
  • Full Text URL
    journals.iucr.org/e/issues/2017/02/00/wm5352/wm5352.pdf
  • Record number

    2621220

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=2621220