• Title of article

    Crystal structure of μ6-chlorido-nona­kis­(μ-4-chloro­pyrazolato)bis-μ3-methoxo-hexa­copper(II)

  • Author/Authors

    Shi, Kaige Department of Chemistry and Biochemistry - Florida International University, USA , Mathivathanan, Logesh Department of Chemistry and Biochemistry - Florida International University, USA , Raptis, Raphael G. Department of Chemistry and Biochemistry - Florida International University, USA

  • Pages
    10
  • From page
    1
  • To page
    10
  • Abstract
    The hexa­nuclear title compound, [{Cu3(μ3-OCH3)(μ-C3H2ClN2)3}2(μ-C3H2ClN2)3(μ6-Cl)] or [Cu6(C3H2ClN2)9(CH3O)2Cl], crystallizes in the space group Pbcn, with individual mol­ecules being located on a twofold rotation axis. The mol­ecule adopts a trigonal prismatic shape, with two trinuclear units linked by three 4-chloro­pyrazolate ligand bridges by encapsulating a Cl− anion in a μ6-coordination mode. In the crystal, individual mol­ecules are stacked into rods parallel to [1-10] that are arranged in a pseudo-hexa­gonal packing. Cohesion between mol­ecules is accomplished through weak C—H⋯Cl inter­actions.
  • Keywords
    trigonal prismatic hexa­nuclear copper pyrazolate , chloride encapsulation , μ6-Cl coordination; , crystal structure
  • Journal title
    Acta Crystallographica Section E: Crystallographic Communications
  • Serial Year
    2017
  • Full Text URL
    journals.iucr.org/e/issues/2017/02/00/wm5353/wm5353.pdf
  • Record number

    2621314

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=2621314