Title of article :
Crystal structure of trans-dichloridobis[N-(5,5-dimethyl-4,5-dihydro-3H-pyrrol-2-yl-κN)acetamide]palladium(II) dihydrate
Author/Authors :
Lasri, Jamal Department of Chemistry - Rabigh College of Science and Arts, Saudi Arabia , Eltayeb, Naser Eltaher Department of Chemistry - Rabigh College of Science and Arts, Saudi Arabia , Haukka, Matti University of Jyväskylä - Department of Chemistry - University of Jyväskylä, Finland , Babgi, Bandar A. Department of Chemistry - Rabigh College of Science and Arts, Saudi Arabia
Abstract :
The title complex, [PdCl2(C8H14N2O)2]·2H2O, was obtained by N–O bond cleavage of the oxadiazoline rings of the trans-[dichlorido-bis(2,5,5-trimethyl-5,6,7,7a-tetrahydropyrrolo[1,2-b][1,2,4]oxadiazole-N1)]palladium(II) complex. The palladium(II) atom exhibits an almost square-planar coordination provided by two trans-arranged chloride anions and a nitrogen atom from each of the two neutral organic ligands. In the crystal, N—H⋯O, O—H⋯O and O—H⋯Cl hydrogen bonds link complex molecules into double layers parallel to the bc plane.
Keywords :
crystal structure , N—O bond cleavage , cycloaddition , nitrone , palladium
Journal title :
Acta Crystallographica Section E: Crystallographic Communications
