Title of article :
Crystal structure of N-(2-benzoyl-5-ethynylphen­yl)quinoline-2-carboxamide
Author/Authors :
Peña-Solórzano, Diana Grupo de Investigación en Macromoléculas - Departamento de Química - Universidad Nacional de Colombia-Sede Bogotá, Colombia , Königb, Burkhard Institute of Organic Chemistry - University of Regensburg, Germany , Sierra, Cesar A. Grupo de Investigación en Macromoléculas - Departamento de Química - Universidad Nacional de Colombia-Sede Bogotá, Colombia , Ochoa-Puentes, Cristian Grupo de Investigación en Macromoléculas - Departamento de Química - Universidad Nacional de Colombia-Sede Bogotá, Colombia
Pages :
10
From page :
1
To page :
10
Abstract :
In the title compound, C25H16N2O2, the quinoline ring system is essentially planar, with a maximum deviation of 0.030 (1) Å, and forms a dihedral angle of 20.9 (1)° with benzoyl benzene ring. The unsubstituted phenyl ring forms dihedral angles of 52.7 (1)° with the quinoline ring system and 54.1 (1)° with the ethynyl-substituted benzene ring. The mol­ecule contains an intra­molecular bifurcated N—H⋯(O,N) hydrogen bond, forming S(5) and S(6) rings, which may influence the conformation of the mol­ecule. In the crystal, weak C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network. In addition, the three-dimensional structure contains π–π stacking inter­actions, with centroid–centroid distances of 3.695 (1) and 3.751 (1) Å.
Keywords :
crystal structure , quinoline , benzoyl-5-ethynylphen­yl , hydrogen bonding
Journal title :
Acta Crystallographica Section E: Crystallographic Communications
Serial Year :
2017
Full Text URL :
Record number :
2621604
Link To Document :
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