• Title of article

    Crystal structures of the polymer precursors 3-(2,5-dimeth­­oxy-3,4,6-tri­methyl­phen­yl)propyl methacrylate and 3-(2,4,5-tri­methyl-3,6-dioxo­cyclo­hexa-1,4-dien­yl)propyl methacrylate

  • Author/Authors

    Goswami, Shailesh K. Department of Chemistry - University of Otago, New Zealand , Hanton, Lyall R. Department of Chemistry - University of Otago, New Zealand , McAdam, C. John Department of Chemistry - University of Otago, New Zealand , Moratti, tephen C. Department of Chemistry - University of Otago, New Zealand , Simpson, Jim Department of Chemistry - University of Otago, New Zealand

  • Pages
    16
  • From page
    1
  • To page
    16
  • Abstract
    The closely related title compounds, 3-(2,5-dimeth­oxy-3,4,6-tri­methyl­phen­yl)propyl methacrylate, C18H26O4 (I), and 3-(2,4,5-trimethyl-3,6-dioxo­cyclo­hexa-1,4-dien­yl)propyl methacrylate, C16H20O4 (II), are monomers suitable for the preparation of redox polymers. They consist of a propyl­methacrylate group and three methyl substituents on di­meth­oxy­benzene and quinone cores, respectively. Both crystal structures feature weak C—H⋯O hydrogen bonds and C—H⋯π(ring) contacts between methyl groups and the six-membered rings.
  • Keywords
    crystal structure , methacrylate , di­meth­oxy­benzene , quinone , hydrogen bonds , C—H⋯π contacts
  • Journal title
    Acta Crystallographica Section E: Crystallographic Communications
  • Serial Year
    2017
  • Record number

    2621736