Author/Authors :
Binti Mohd Amin, Nur Adibah Department of Chemistry - University of Malaya, Malaysia , Duali Hussen, Rusnah Syahila Department of Chemistry - University of Malaya, Malaysia , Lee, See Mun Research Centre for Crystalline Materials - School of Science and Technology - Sunway University, Malaysia , Halcovitch, Nathan R. Department of Chemistry - Lancaster University, United Kingdom , Jotani, Mukesh M. Department of Physics - Bhavan's Sheth R. A. College of Science, India , Tiekink, Edward R. T. Research Centre for Crystalline Materials - School of Science and Technology - Sunway University, Malaysia
Abstract :
The SnIV atom in the title diorganotin compound, [Sn(C7H6F)2Cl2(C2H6OS)2], is located on a centre of inversion, resulting in the C2Cl2O2 donor set having an all-trans disposition of like atoms. The coordination geometry approximates an octahedron. The crystal features C—H⋯F, C—H⋯Cl and C—H⋯π interactions, giving rise to a three-dimensional network. The respective influences of the Cl⋯H/H⋯Cl and F⋯H/H⋯F contacts to the molecular packing are clearly evident from the analysis of the Hirshfeld surface.
Keywords :
crystal structure , organotin , Hirshfeld surface analysis , C—H⋯F interactions
