Title of article :
An infinite two-dimensional hybrid water–chloride network in a 4′-(furan-2-yl)-2,2′:6′,2′′-terpyridine nickel(II) matrix
Author/Authors :
Fu, Wei-Wei Key Laboratory of Functional Organometallic Materials of General Colleges and Universities in Hunan Province - Department of Chemistry and Materials Science - Hengyang Normal University - People's Republic of China , Li, Ya-Qian Key Laboratory of Functional Organometallic Materials of General Colleges and Universities in Hunan Province - Department of Chemistry and Materials Science - Hengyang Normal University - People's Republic of China , Liu,Yang Key Laboratory of Functional Organometallic Materials of General Colleges and Universities in Hunan Province - Department of Chemistry and Materials Science - Hengyang Normal University - People's Republic of China , Chen, Man-Sheng Key Laboratory of Functional Organometallic Materials of General Colleges and Universities in Hunan Province - Department of Chemistry and Materials Science - Hengyang Normal University - People's Republic of China , Li, Wei Key Laboratory of Functional Organometallic Materials of General Colleges and Universities in Hunan Province - Department of Chemistry and Materials Science - Hengyang Normal University - People's Republic of China , Yang, Ying-Qun Key Laboratory of Functional Organometallic Materials of General Colleges and Universities in Hunan Province - Department of Chemistry and Materials Science - Hengyang Normal University - People's Republic of China
Abstract :
A new complex, namely bis[4′-(furan-2-yl)-2,2′:6′,2′′-terpyridine]nickel(II) dichloride decahydrate, [Ni(C19H13N3O)2]Cl2·10H2O, has been crystallized by solvent evaporation and characterized by single-crystal X-ray diffraction. The coordination environment of the NiII cation is distorted octahedral with slight deviations from an idealized geometry. The most intriguing structural feature is an infinite two-dimensional hybrid water–chloride network parallel to (011) constructed by O—H⋯O and O—H⋯Cl hydrogen bonds involving two independent chloride ions and ten independent solvent water molecules with an L-shaped pattern. One of the furyl rings is disordered with a refined occupancy ratio of 0.786 (13):0.214 (13)
Keywords :
crystal structure , terpyridine , hydrogen bonds , water–chloride network , water cluster , NiII
Journal title :
Acta Crystallographica Section E: Crystallographic Communications
