Practical hints and tips for solution of pseudo-merohedric twins: three case studies

Twinning by pseudo-merohedry is a common phenomenon in small-mol­ecule crystallography. In cases where twin-component volume fractions are markedly different, structure solution is often no more difficult than for non-twinned structures of similar complexity. When twin-component volume fractions are similar, however, structure solution can be much more of a problem. This paper presents hints and tips for such cases by means of three worked examples. The first example presents the most common (and simplest) case of a two-component pseudo-ortho­rhom­bic twin. The second example describes structure solution of a reticular threefold pseudo-hexa­gonal twin that benefits from use of an unconventional space-group setting. The third example covers structure solution of a reticular fourfold pseudo-tetra­gonal twin. All three structures are ultimately shown to be monoclinic crystals that twin as a consequence of unit-cell metrics that mimic those of higher symmetry crystal systems.