• Title of article

    Crystallographic characterization of (C5H4SiMe3)3U(BH4)

  • Author/Authors

    Windorff, Cory J. Los Alamos National Laboratory, Los Alamos, USA , Cross, Justin N. Los Alamos National Laboratory, Los Alamos, USA , Scott, Brian L. Los Alamos National Laboratory, Los Alamos, USA , Kozimor, Stosh A. Los Alamos National Laboratory, Los Alamos, USA , Evans, William J. Department of Chemistry - University of California, USA

  • Pages
    15
  • From page
    1
  • To page
    15
  • Abstract
    New syntheses have been developed for the synthesis of (borohydrido- 3H)tris[5 -(trimethylsilyl)cyclopentadienyl]uranium(IV), [U(BH4)(C8H13Si)3] or Cp0 3U(BH4) (Cp0 = C5H4SiMe3) and its structure has been determined by single-crystal X-ray crystallography. This compound crystallized in the space group P1 and the structure features three 5 -coordinated Cp0 rings and a 3-coordinated (BH4) ligand.
  • Keywords
    crystal structure , uranium , borohydride , cyclo­penta­dienyl compounds
  • Journal title
    Acta Crystallographica Section E: Crystallographic Communications
  • Serial Year
    2021
  • Record number

    2622116