• Title of article

    Two salts of the 6,6-di­fluoro-6H-dibenzo[c,e][1,2]oxaborinin-6-ide anion with different cations

  • Author/Authors

    Budanow, Alexandra Institut für Anorganische und Analytische Chemie - Goethe-Universität Frankfurt, Germany , Lerner, Hans-Wolfram Institut für Anorganische und Analytische Chemie - Goethe-Universität Frankfurt, Germany , Bolte, Michael Institut für Anorganische und Analytische Chemie - Goethe-Universität Frankfurt, Germany

  • Pages
    23
  • From page
    1
  • To page
    23
  • Abstract
    The crystal structures are reported of the 6,6-di­fluoro-6H-dibenzo[c,e][1,2]oxaborinin-6-ide (or 9,9-di­fluoro-10-oxa-9-boraphenanthren-9-ide) anion with two different cations, namely, potassium 6,6-di­fluoro-6H-dibenzo[c,e][1,2]oxaborinin-6-ide, K+·C12H8BF2O−, (II), featuring a polymeric structure, and bis­(tetra­phenyl­phospho­nium) bis­(6,6-di­fluoro-6H-dibenzo[c,e][1,2]oxaborinin-6-ide) aceto­nitrile tris­olvate, 2C24H20P+·2C12H8BF2O−·3CH3CN, (III), which is composed of discrete cations, anions and aceto­nitrile solvent mol­ecules linked by C—H⋯O, C—H⋯N and C—H⋯F hydrogen bonds. There are only minor differences in the geometrical parameters of the anions in these structures.
  • Keywords
    crystal structure , boron , potassium , fluorine
  • Journal title
    Acta Crystallographica Section E: Crystallographic Communications
  • Serial Year
    2020
  • Full Text URL
    journals.iucr.org/e/issues/2020/12/00/hb7952/hb7952.pdf
  • Record number

    2622514

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=2622514