Title of article :
Crystal structure of bis[μ-N-(η2-prop-2-en-1-yl)piperidine-1-carbothioamide-κ2S:S]bis[(thiocyanato-κN)copper(I)]
Author/Authors :
Tanaka, Takeshi Osaka Research Institute of Industrial Science and Technology, Japan , Kashiwagi, Yukiyasu Osaka Research Institute of Industrial Science and Technology, Japan , Nakagawa, Masami Osaka Research Institute of Industrial Science and Technology, Japan
Abstract :
The title crystalline compound, [Cu2(NCS)2(C9H16N2)2], was obtained from the reaction of copper(I) thiocyanate (CuSCN) with (N-prop-2-en-1-yl)piperidine-1-carbothioamide as a chelating and bridging thiourea ligand in chlorobenzene. The Cu2S2 core of the dimeric molecule is situated on a crystallographic inversion centre. The copper atom is coordinated by a thiocyanate nitrogen atom, each sulfur atom of the two thiourea ligands, and the C=C double bond of the ligand in a distorted tetrahedral geometry. The dimers are linked by N—H⋯S hydrogen bonds, forming a network extending in two dimensions parallel to (100).
Keywords :
η2-π-allyl coordination , C—H⋯S interaction , N—H⋯S interaction , thiourea , CuI dimer , crystal structure
Journal title :
Acta Crystallographica Section E: Crystallographic Communications
