Title of article
Crystal structure and fluorescence study of (μ-N-[(3,5-dimethyl-1H-pyrrol-2-yl)methylidene]-N-{4-[(3,5-dimethyl-1H-pyrrol-2-yl)methylideneazaniumyl]phenyl}azanium)bis[difluoridoboron(IV)]
Author/Authors
Liu, Xiaoxue College of Chemistry - Tianjin Key Laboratory of Structure and Performance for Functional Molecule, People's Republic of China , Li, Tuo College of Chemistry - Tianjin Key Laboratory of Structure and Performance for Functional Molecule, People's Republic of China , Yin, Zhenming College of Chemistry - Tianjin Key Laboratory of Structure and Performance for Functional Molecule, People's Republic of China
Pages
10
From page
1
To page
10
Abstract
The title molecule, C20H20B2F4N4, assumes a planar conformation with all atoms apart from the F atoms lying on the symmetry plane. Each boron atom is four-coordinated by two fluorine atoms, a pyrrole N atom and an imine N atom. Both imine CH=N groups adopt a trans conformation. In the crystal, the molecules self-assemble into a pillar structure through C—H⋯F hydrogen bonds and π–π interactions. The UV–vis spectrum and fluorescence spectra of the title compound are also reported.
Keywords
2-iminopyrrole , BF2 complex , crystal structure , fluorescence.
Journal title
Acta Crystallographica Section E: Crystallographic Communications
Serial Year
2021
Record number
2622875
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