Title of article
Crystal structure of 7,7′-[(pyridin-2-yl)methylene]bis(5-chloroquinolin-8-ol)
Author/Authors
Kashiwagi, Yukiyasu Osaka Research Institute of Industrial Science and Technology, Japan , Kubono, Koji Osaka Kyoiku University, Kashiwara, Japan , Tamai, Toshiyuki Osaka Research Institute of Industrial Science and Technology, Japan
Pages
10
From page
1
To page
10
Abstract
In the title compound, C24H15Cl2N3O2, one quinoline ring system is essentially planar and the other is slightly bent. An intramolecular O—H⋯N hydrogen bond involving the hydroxy group and a pyridine N atom forms an S(5) ring motif. In the crystal, two molecules are associated into an inversion dimer with two R22(7) ring motifs through intermolecular O—H⋯N and O—H⋯O hydrogen bonds. The dimers are further linked by an intermolecular C—H⋯O hydrogen bond and four C—H⋯π interactions, forming a two-dimensional network parallel to (001).
Keywords
crystal structure , C—H⋯π interactions , tridentate ligand , bridging ligand , 8-quinolinol
Journal title
Acta Crystallographica Section E: Crystallographic Communications
Serial Year
2020
Record number
2623042
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