• Title of article

    Synthesis and crystal structure of [Zn6Br4(C9H18NO)4(OH)4]·2C3H6O2

  • Author/Authors

    Scheela, Rebecca Inorganic Chemistry - TU Dortmund University, Germany , Brieger, Lukas Inorganic Chemistry - TU Dortmund University, Germany , Louven, Kathrin Inorganic Chemistry - TU Dortmund University, Germany , Strohmann, Carsten Inorganic Chemistry - TU Dortmund University, Germany

  • Pages
    13
  • From page
    1
  • To page
    13
  • Abstract
    The complete mol­ecule of the hexa­metallic title complex, namely, tetra­bromido­tetra-μ-hydroxido-hexa­kis­[μ-2-methyl-3-(pyrrolidin-1-yl)propan-2-olato]hexa­zinc(II) acetone disolvate, [Zn6Br4(C9H18NO)4(OH)4]·2C3H6O2, is generated by a crystallographic centre of symmetry. Two of the unique zinc atoms adopt distorted ZnO2NBr tetra­hedral coordination geometries and the other adopts a ZnO3N tetra­hedral arrangement. Both unique alkoxide ligands are N,O-chelating and both hydroxide ions are μ2 bridging. The crystal structure displays an O—H⋯O hydrogen bond between a μ2-OH group and an acetone solvent mol­ecule. The Hirshfeld surface has been calculated and is described
  • Keywords
    crystal structure , hydrogen bonding , hydroxide , zinc , amino­alkoxide , zinc alkoxide
  • Journal title
    Acta Crystallographica Section E: Crystallographic Communications
  • Serial Year
    2020
  • Full Text URL
    ournals.iucr.org/e/issues/2020/07/00/hb7910/hb7910.pdf
  • Record number

    2623496

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=2623496