• Title of article

    Crystal structure of SrCo4(OH)(PO4)3, a new hy­dr­oxy­phosphate

  • Author/Authors

    Cherif, Fatima-Zahra Laboratoire de Chimie Appliquée des Matériaux, Centre des Sciences des Matériaux - Faculty of Science - Mohammed V University in Rabat, Morocco , Taibi, Mhamed Laboratoire de Physico-Chimie des Matériaux Inorganiques et Organiques - Centre des Sciences des Matériaux - Ecole Normale Supérieure - Mohammed V University in Rabat, Morocco , Boukhari, Ali Laboratoire de Chimie Appliquée des Matériaux, Centre des Sciences des Matériaux - Faculty of Science - Mohammed V University in Rabat, Morocco , Aride, Jilali Laboratoire de Physico-Chimie des Matériaux Inorganiques et Organiques - Centre des Sciences des Matériaux - Ecole Normale Supérieure - Mohammed V University in Rabat, Morocco , Assani, Abderrazzak Laboratoire de Chimie Appliquée des Matériaux, Centre des Sciences des Matériaux - Faculty of Science - Mohammed V University in Rabat, Morocco , Saadi, Mohamed Laboratoire de Chimie Appliquée des Matériaux, Centre des Sciences des Matériaux - Faculty of Science - Mohammed V University in Rabat, Morocco , Ammari, Lahcen El Laboratoire de Chimie Appliquée des Matériaux, Centre des Sciences des Matériaux - Faculty of Science - Mohammed V University in Rabat, Morocco

  • Pages
    10
  • From page
    1
  • To page
    10
  • Abstract
    Single crystals of strontium tetra­cobalt tris­(orthophosphate) hydroxide, SrCo4(OH)(PO4)3, were grown serendipitously under hydro­thermal conditions at 473 K. The crystal structure consists of undulating chains of edge-sharing [CoO6] octa­hedra that are linked into (010) layers by common vertices between chains. Adjacent layers are linked along [010] into a framework structure by tetra­hedral [CoO4] units and by PO4 tetra­hedra. The framework delimits channels extending along [100] in which the eleven-coordinate strontium cations are situated. Bifurcated O—H⋯O hydrogen bonds of weak strengths consolidate the crystal packing. The title compound was also characterized by infrared spectroscopy.
  • Keywords
    infrared spectroscopy , crystal structure , orthophosphate , cobal , strontium , bifurcated hydrogen bonding
  • Journal title
    Acta Crystallographica Section E: Crystallographic Communications
  • Serial Year
    2020
  • Full Text URL
    journals.iucr.org/e/issues/2020/07/00/wm5562/wm5562.pdf
  • Record number

    2623501

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=2623501