Title of article :
Crystal structure and Hirshfeld surface analysis of 4-{[(anthracen-9-yl)meth­yl]amino}­benzoic acid di­methyl­formamide monosolvate
Author/Authors :
Ahmed, Adeeba Department of Applied Chemistry, ZHCET - Aligarh Muslim University, India , Ahmad, Aiman Department of Applied Chemistry, ZHCET - Aligarh Muslim University, India , Ahmad, Musheer Department of Applied Chemistry, ZHCET - Aligarh Muslim University, India , Kalibabchuk, Valentina A. Department of General Chemistry - O. O. Bohomolets National Medical University, Ukraine
Pages :
9
From page :
1
To page :
9
Abstract :
The title compound, C22H17NO2·C3H7NO, was synthesized by condensation of an aromatic aldehyde with a secondary amine and subsequent reduction. It was crystallized from a di­methyl­formamide solution as a monosolvate, C22H17NO2·C3H7NO. The aromatic mol­ecule is non-planar with a dihedral angle between the mean planes of the aniline moiety and the methyl anthracene moiety of 81.36 (8)°. The torsion angle of the Car­yl—CH2—NH—Car­yl backbone is 175.9 (2)°. The crystal structure exhibits a three-dimensional supra­molecular network, resulting from hydrogen-bonding inter­actions between the carb­oxy­lic OH group and the solvent O atom as well as between the amine functionality and the O atom of the carb­oxy­lic group and additional C—H⋯π inter­actions. Hirshfeld surface analysis was performed to qu­antify the inter­molecular inter­actions.
Keywords :
crystal structure , 4-amino­benzoic acid (PABA) , anthracene , inter­molecular hydrogen bonding , C—H⋯π inter­actions , Hirshfeld surface analysis
Journal title :
Acta Crystallographica Section E: Crystallographic Communications
Serial Year :
2020
Full Text URL :
Record number :
2624074
Link To Document :
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