Title of article :
The synthesis, crystal structure and Hirshfeld analysis of 4-(3,4-dimethylanilino)-N-(3,4-dimethylphenyl)quinoline-3-carboxamide
Author/Authors :
Gomes, Ligia R. REQUIMTE, Departamento de Química e Bioquímica - Faculdade de Ciências da Universidade do Porto, Portugal , Nicolson Low, John Department of Chemistry - University of Aberdeen, Scotland , Borges, Fernanda CIQUP Departamento de Quιmica e Bioquιmica - Faculdade de Ciências - Universidade do Porto, Portugal , Gaspar, Alexandra CIQUP Departamento de Quιmica e Bioquιmica - Faculdade de Ciências - Universidade do Porto, Portugal , Mesiti, Francesco Department of "Scienze della Vita" - University "Magna Graecia" of Catanzaro, Catanzaro, Italy
Abstract :
The structure of the title quinoline carboxamide derivative, C26H25N3O, is described. The quinoline moiety is not planar as a result of a slight puckering of the pyridine ring. The secondary amine has a slightly pyramidal geometry, certainly not planar. Both intra- and intermolecular hydrogen bonds are present. Hirshfeld surface analysis and lattice energies were used to investigate the intermolecular interactions.
Keywords :
crystal structure , hydrogen bonding , quinoline , carboxamide , amine
