• Title of article

    Crystal structure of 4-bromo-N-[(3,6-di-tert-butyl-9H-carbazol-1-yl)methyl­­idene]aniline

  • Author/Authors

    Kubono, Koji Division of Natural Sciences - Osaka Kyoiku University, Japan , Matsumoto, Taisuke Institute for Materials Chemistry and Engineering - Kyushu University, Japan , Taneda, Masatsugu Department of Science Education - Faculty of Education - Osaka Kyoiku University, Kashiwara, Japan

  • Pages
    10
  • From page
    1
  • To page
    10
  • Abstract
    In the title compound, C27H29BrN2, the carbazole ring system is essentially planar, with an r.m.s. deviation of 0.0781 (16) Å. An intra­molecular N—H⋯N hydrogen bond forms an S(6) ring motif. One of the tert-butyl substituents shows rotational disorder over two sites with occupancies of 0.592 (3) and 0.408 (3). In the crystal, two mol­ecules are associated into an inversion dimer through a pair of C—H⋯π inter­actions. The dimers are further linked by another pair of C—H⋯π inter­actions, forming a ribbon along the c-axis direction. A C—H⋯π inter­action involving the minor disordered component and the carbazole ring system links the ribbons, generating a network sheet parallel to (100).
  • Keywords
    crystal structure , carbazole , Schiff base , intra­molecular hydrogen bond , C—H⋯π inter­action
  • Journal title
    Acta Crystallographica Section E: Crystallographic Communications
  • Serial Year
    2019
  • Record number

    2625268