Title of article :
Crystal structure of 4-bromo-N-[(3,6-di-tert-butyl-9H-carbazol-1-yl)methyl­­idene]aniline
Author/Authors :
Kubono, Koji Division of Natural Sciences - Osaka Kyoiku University, Japan , Matsumoto, Taisuke Institute for Materials Chemistry and Engineering - Kyushu University, Japan , Taneda, Masatsugu Department of Science Education - Faculty of Education - Osaka Kyoiku University, Kashiwara, Japan
Pages :
10
From page :
1
To page :
10
Abstract :
In the title compound, C27H29BrN2, the carbazole ring system is essentially planar, with an r.m.s. deviation of 0.0781 (16) Å. An intra­molecular N—H⋯N hydrogen bond forms an S(6) ring motif. One of the tert-butyl substituents shows rotational disorder over two sites with occupancies of 0.592 (3) and 0.408 (3). In the crystal, two mol­ecules are associated into an inversion dimer through a pair of C—H⋯π inter­actions. The dimers are further linked by another pair of C—H⋯π inter­actions, forming a ribbon along the c-axis direction. A C—H⋯π inter­action involving the minor disordered component and the carbazole ring system links the ribbons, generating a network sheet parallel to (100).
Keywords :
crystal structure , carbazole , Schiff base , intra­molecular hydrogen bond , C—H⋯π inter­action
Journal title :
Acta Crystallographica Section E: Crystallographic Communications
Serial Year :
2019
Full Text URL :
Record number :
2625268
Link To Document :
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