• Title of article

    Crystal structure of catena-poly[[bis­(3-oxo-1,3-di­phenyl­prop-1-enolato-κ2O,O′)zinc(II)]-μ2-tris­[4-(pyridin-3-yl)phen­yl]amine-κ2N:N′] tetra­hydro­furan monosolvate]

  • Author/Authors

    Kubono, Koji Osaka Kyoiku University, Kashiwara, Japan , Kashiwagi, Yukiyasu Osaka Research Institute of Industrial Science and Technology, Japan , Tamai, Toshiyuki Osaka Research Institute of Industrial Science and Technology, Japan

  • Pages
    17
  • From page
    1
  • To page
    17
  • Abstract
    The reaction of bis­(3-oxo-1,3-di­phenyl­prop-1-enolato-κ2O,O′)zinc(II), [Zn(dbm)2], with tris­[4-(pyridin-3-yl)phen­yl]amine (T3PyA) in tetra­hydro­furan (THF) afforded the title crystalline coordination polymer, {[Zn(C15H11O2)2(C33H24N4)]·C4H8O}n. The asymmetric unit contains two independent halves of Zn(dbm)2, one T3PyA and one THF. Each ZnII atom is located on an inversion centre and adopts an elongated octa­hedral coordination geometry, ligated by four O atoms of two dbm ligands in equatorial positions and by two N atoms of pyridine moieties from two different bridging T3PyA ligands in axial positions. The crystal packing shows a one-dimensional polymer chain in which the two pyridyl groups of the T3PyA ligand bridge two independent Zn atoms of Zn(dbm)2. In the crystal, the coordination polymer chains are linked via C—H⋯π inter­actions into a sheet structure parallel to (010). The sheets are cross-linked via further C—H⋯π inter­actions into a three-dimensional network. The solvate THF mol­ecule shows disorder over two sets of atomic sites having occupancies of 0.631 (7) and 0.369 (7).
  • Keywords
    C—H⋯π inter­actions , crystal structure , coordination polymer , tri­aryl­amine , β-diketonato zinc(II)
  • Journal title
    Acta Crystallographica Section E: Crystallographic Communications
  • Serial Year
    2019
  • Record number

    2625269