• Title of article

    The crystal structure of ((cyclo­hexyl­amino){(Z)-2-[(E)-5-meth­­oxy-3-nitro-2-oxido­benzyl­­idene-κO]hydrazin-1-yl­­idene-κN2}methane­thiol­ato-κS)(di­methyl sulfoxide-κS)platinum(II): a supra­molecular two-dimensional network

  • Author/Authors

    Arafath, Md. Azharul Department of Chemistry - Shahjalal University of Science and Technology, Bangladesh , Kwong, Huey Chong School of Chemical Sciences - Universiti Sains Malaysia, Malaysia , Adam, Farook School of Chemical Sciences - Universiti Sains Malaysia, Malaysia

  • Pages
    10
  • From page
    1
  • To page
    10
  • Abstract
    The PtII atom in the title complex, [Pt(C15H18N4O4S)(C2H6OS)], exists within a square-planar NS2O donor set provided by the N, S, O atoms of the di-anionic tridentate thio­semicarbazo ligand and a dimethyl sulfoxide S atom. The two chelate rings are coplanar, subtending a dihedral angle of 1.51 (7)°. The maximum deviation from an ideal square-planar geometry is seen in the five-membered chelate ring with an S—Pt—S bite angle of 96.45 (2)°. In the crystal, mol­ecules are linked via N—H⋯O, C—H⋯O, C—H⋯N and C—H⋯π inter­actions into two-dimensional networks lying parallel to the ab plane. The conformations of related cyclo­hexyl­hydrazine-1-carbo­thio­amide ligands are compared to that of the title compound.
  • Keywords
    C—H⋯π inter­actions , crystal structure , cyclo­hexyl­hydrazinecarbo­thio­amide , soft Lewis base , carbo­thio­amide Schiff base , hydrogen bonding
  • Journal title
    Acta Crystallographica Section E: Crystallographic Communications
  • Serial Year
    2019
  • Record number

    2625278