• Title of article

    Synthesis and crystal structure of tert-butyl 1-(2-iodo­benzo­yl)cyclo­pent-3-ene-1-carboxyl­ate

  • Author/Authors

    Yin, Dejing School of Biotechnology - Jiangnan University, People's Republic of China

  • Pages
    8
  • From page
    1
  • To page
    8
  • Abstract
    1-(2-Iodo­benzo­yl)-cyclo­pent-3-ene-1-carboxyl­ates are novel substrates to construct bi­cyclo­[3.2.1]octa­nes with anti­bacterial and anti­thrombotic activities. In this context, tert-butyl 1-(2-iodo­benzo­yl)-cyclo­pent-3-ene-1-carboxyl­ate, C17H19IO3, was synthesized and structurally characterized. The 2-iodo­benzoyl group is attached to the tertiary C atom of the cyclo­pent-3-ene ring. The dihedral angle between the benzene ring and the mean plane of the envelope-type cyclo­pent-3-ene ring is 26.0 (3)°. In the crystal, pairs of C-H⋯O hydrogen bonds link the mol­ecules to form inversion dimers.
  • Keywords
    crystal structure , substrate , cyclo­pentene ring , hydrogen bonding
  • Journal title
    Acta Crystallographica Section E: Crystallographic Communications
  • Serial Year
    2019
  • Record number

    2625362