• Title of article

    Crystal structure of bis­­[di­hydro­bis­­(pyrazol-1-yl)borato-κ2N2,N2′](1,10-phenanthroline-κ2N,N′)zinc(II)

  • Author/Authors

    Ossinger, Sascha Institut für Anorganische Chemie - Christian-Albrechts-Universität Kiel, Germany , Näther, Christian Institut für Anorganische Chemie - Christian-Albrechts-Universität Kiel, Germany , Tuczek, Felix Institut für Anorganische Chemie - Christian-Albrechts-Universität Kiel, Germany

  • Pages
    9
  • From page
    1
  • To page
    9
  • Abstract
    The asymmetric unit of the title compound, [Zn(C6H8N4B)2(C12H8N2)], comprises one half of a ZnII cation (site symmetry 2), one di­hydro­bis­(pyrazol-1-yl)borate ligand in a general position, and one half of a phenanthroline ligand, the other half being completed by twofold rotation symmetry. The ZnII cation is coordinated in form of a slightly distorted octa­hedron by the N atoms of a phenanthroline ligand and by two pairs of N atoms of symmetry-related di­hydro­bis­(pyrazol-1-yl)borate ligands. The discrete complexes are arranged into columns that elongate in the c-axis direction with a parallel alignment of the phenanthroline ligands, indicating weak π–π inter­actions.
  • Keywords
    crystal structure , model substance for FeII di­hydro­bis­(pyrazol-1-yl)borate phenanthroline , ZnII
  • Journal title
    Acta Crystallographica Section E: Crystallographic Communications
  • Serial Year
    2019
  • Record number

    2625385