• Title of article

    Structure and Hirshfeld surface analysis of the salt N,N,N-tri­methyl-1-(4-vinyl­phen­yl)methanaminium 4-vinyl­benzene­sulfonate

  • Author/Authors

    McAdam, C. John Department of Chemistry - University of Otago, New Zealand , Hanton, Lyall R. Department of Chemistry - University of Otago, New Zealand , Moratti, Stephen C. Department of Chemistry - University of Otago, New Zealand , Simpson, Jim Department of Chemistry - University of Otago, New Zealand , Wickramasinhage, Ravindra N. Department of Chemistry - University of Otago, New Zealand

  • Pages
    11
  • From page
    1
  • To page
    11
  • Abstract
    In the title compound, the asymmetric unit comprises an N,N,N-trimethyl-1-(4-vinyl­phen­yl)methanaminium cation and a 4-vinyl­benzene­sulfonate anion, C12H18N+·C8H7O3S−. The salt has a polymerizable vinyl group attached to both the cation and the anion. The methanaminium and vinyl substituents on the benzene ring of the cation subtend angles of 86.6 (3) and 10.5 (9)° to the ring plane, while the anion is planar excluding the sulfonate O atoms. The vinyl substituent on the benzene ring of the cation is disordered over two sites with a refined occupancy ratio of 0.542 (11):0.458 (11). In the crystal, C—H⋯O hydrogen bonds dominate the packing and combine with a C—H⋯π(ring) contact to stack the cations and anions along the a-axis direction. Hirshfeld surface analysis of the salt and of the individual cation and anion components is also reported.
  • Keywords
    crystal structure , N,N,N-trimethyl-1-(4-vinyl­phen­yl)methanaminium cation , 4-vinyl­benzene­sulfonate anion , hydrogen bonds , Hirshfeld surface analysis
  • Journal title
    Acta Crystallographica Section E: Crystallographic Communications
  • Serial Year
    2019
  • Record number

    2625448