SPECTRAL STUDIES an‎d CHARACTERIZATION OF Cr(III) COMPLEXES WITH SOME NITROGEN-OXYGEN an‎d NITROGEN-SULPHUR DONOR LIGANDS

Cr(III) complexes are synthesized with thiosemicarbazones (L^1, L^3 and L^5) and semicarbazones (L^2, L^4and L^6) derived from pyrrole-2-carboxyaldehyde, 2-acetyl furan and 2-acetyl thiophene. These arecharacterized by elemental analysis, molar conductance, magnetic susceptibility measurements, mass, IR,electronic and EPR spectral studies. The molar conductance measurement of the complexes in DMSOcorresponds to 1:1 electrolyte in nature. On the basis of spectral studies an octahedral geometry has beenassigned for all the complexes.