Author/Authors :
Bouzian, Younos Laboratoire de Chimie Organique Hétérocyclique - Centre de Recherche Des Sciences des Médicaments - Pôle de Compétence Pharmacochimie, Morocco , Haque Faizi,Md. Serajul Department of Chemistry - Langat Singh College - Babasaheb Bhimrao Ambedkar Bihar University, India , Mague, Joel T. Department of Chemistry - Tulane University, USA , Otmani, Bouchaib El Laboratoire de Chimie Organique Hétérocyclique - Centre de Recherche Des Sciences des Médicaments - Pôle de Compétence Pharmacochimie, Morocco , Dege, Necmi Ondokuz Mayıs University - Faculty of Arts and Sciences - Department of Physics, Turkey , Karrouchi, Khalid Laboratory of Plant Chemistry - Organic and Bioorganic Synthesis - URAC23, Faculty of Science, Morocco , Essassi, El Mokhtar Laboratoire de Chimie Organique Hétérocyclique - Centre de Recherche Des Sciences des Médicaments - Pôle de Compétence Pharmacochimie, Morocco
Abstract :
In the title quinoline derivative, C24H19NO3, the two benzyl rings are inclined to the quinoline ring mean plane by 74.09 (8) and 89.43 (7)°, and to each other by 63.97 (10)°. The carboxylate group is twisted from the quinoline ring mean plane by 32.2 (2)°. There is a short intramolecular C—H⋯O contact forming an S(6) ring motif. In the crystal, molecules are linked by bifurcated C—H,H⋯O hydrogen bonds, forming layers parallel to the ac plane. The layers are linked by C—H⋯π interactions, forming a supramolecular three-dimensional structure.
Keywords :
crystal structure , 2-oxo-1,2-dihydroquinoline , C—H⋯O hydrogen bonding , C—H⋯π interactions , supramolecular three-dimensional structure , DFT
