Title of article :
Crystal structure of di­methyl N,N′-[(ethyne-1,2-di­yl)bis­­(1,4-phenyl­enecarbon­yl)]bis­­(L-alaninate)
Author/Authors :
Eissmann, Frank TU Bergakademie Freiberg, Germany , Seichter, Wilhelm TU Bergakademie Freiberg, Germany , Weber, Edwin TU Bergakademie Freiberg, Germany
Pages :
10
From page :
1
To page :
10
Abstract :
The di­phenyl­ethyne unit of the title mol­ecule, C24H24N2O6, deviates slightly from planarity. The L-alanine moieties adopt distorted helical conformations of opposite winding direction. Infinite ribbons of N—H⋯O=C-connected mol­ecules represent the basic supra­molecular entities of the crystal structure. These aggregates are linked by C—H⋯O hydrogen bonds involving the oxygen atoms of the methyl carboxyl­ate units. The crystal studied was refined as an inversion twin.
Keywords :
N—H⋯O=C and C—H⋯O hydrogen bonding , crystal structure , bis­(L-alaninate) , mol­ecular tape formation
Journal title :
Acta Crystallographica Section E: Crystallographic Communications
Serial Year :
2019
Full Text URL :
Record number :
2628495
Link To Document :
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