Title of article :
SYNTHESIS, CHARACTERIZATION AND X-RAY CRYSTAL STRUCTURE OF 4-(6-AMINO-PYRIDINE-2-YLAMINO)-PENT-3-EN-2-ONE
Author/Authors :
Khalil, Mutasim I. King Saud University - College of Science - Department of Chemistry, Saudi Arabia , Al-Wassil, Abdul Aziz I. King Saud University - College of Science - Dept of Chemistry, Saudi Arabia , Al-Otaibi, Abdullah M. King Saud University - College of Science - Dept of Chemistry, Saudi Arabia. , Seddigi, Zaki S. King Fahd University of Petroleum and Minerals - Chemistry Department, Saudi Arabia , Fettouhi, M. King Fahd University of Petroleum and Minerals - Chemistry Department, Saudi Arabia
Abstract :
The condensation reaction between 2,6-diaminopyridine and acetylacetone in ethyl alcohol under reflex for a prolonged time has resulted in the hitherto unknown 4-(6-Amino pyridine-2-ylamino)-pent-3- en-2- one characterized by FT-IR, 1H, 13C NMR and X-Ray crystallographic techniques. C10H13N3O Crystalizes in the monoclinc space group P2(1)/n with a = 8.4011(10), b = 15.8824(19), c = 15.3714 (19) Å3. The amide group is cis oriented. Geometries were optimized using the Gaussian Go3 program.
Keywords :
condensation , X , ray crystallography , monoclinic , geometries , Gaussian
Journal title :
Journal of Saudi Chemical Society
Journal title :
Journal of Saudi Chemical Society
