Title of article
SYNTHESIS CHARACTERIZATION OF OXAZEPINE AND PYRROLIDIDES FROM REACTION OF N, Ń, Ň-TRIS-(4-DIMETHYLAMINO-BENZYLIDENE)-[1, 3,5]TRIAZENE-2,4,6-TRIAMINE WITH MALEIC,SUCCINIC ANHYDRIDE AND 1H- PYRROLIDENE.
Author/Authors
K, ABDULLAH, H. University of Anbar - College of Education for women - Chemistry of Dept, Iraq , M, BUSHRA, T. University of Anbar - College of Education for women - Chemistry of Dept, Iraq
From page
27
To page
46
Abstract
N,Ń,N-ًTris-(4-dimethylamino-benzylidene)-[1,3,5]triazene-2,4,6- triamine were prepared by condensation of [1,3,5]Triazene-2,4,6-triamine (Melamine) with o-4-dimethylamino- benzaldehyde. These Schiff-bases were reacted with one equivalent of Maleic,Succinic anhydride in absolute ethanol to give 7-membered heterocyclic ring system of 3-{4,6-Bis-[(4-dimethylaminobenzlidene)- amino]-[1,3,5]triazin-2-yl}-2-(4-dimethylamino-phenyl)-2,3-dihydro- [1,3]oxazepine-4,7-dione.Addition of two equivalents of Maleic,Succinic anhydride gave of 8-{4-[(4-dimethylamino-benzylidene)-amino]-6-[4- dimethylamino-phenyl)-4,7-dioxo-4,7-dihydro-[1,3]oxazepine-3-yl]-[1,3,5]triazin- 2-yl}-7-(4-dimethylamino -phenyl)-7,8-dihydro-6-oxa-8-aza-benzocycloheptene- 5,9-dione.i.e, two distant 7-membered rings. Which were reacted with pyrrolidine to give anilid-pyrrolidine derivatives of maleic and Succinic. The synthesized compounds were confirmed by their IR, 1H NMR, UV, spectra and C.H.N. analysis
Keywords
Synthesis Characterization of Oxazepine
Journal title
Journal Of University Of Anbar For Pure Science
Journal title
Journal Of University Of Anbar For Pure Science
Record number
2662901
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