Title of article :
1D Copper(I) Coordination Polymer [Cu2(-L)(-I)2]n: Synthesis, Crystal Structure, Spectral and Thermal Study
Author/Authors :
Mirdarvatan, Vahid Department of Chemistry - Shahrood University of Technology - Shahrood, Iran , Bahramian, Bahram Department of Chemistry - Shahrood University of Technology - Shahrood, Iran , Dehno Khalaji, Aliakbar Department of Chemistry - Faculty of Science - Golestan University - Gorgan, Iran , Peyghoun, Javad Department of Chemistry - Payame Noor University - Mashhad, Iran , Dusek, Michal Institute of Physic of the Czech Academy of Sciences - Na Slovance 2, 182 21 Prague - Czech Republic , Eigner, Vaclav Institute of Physic of the Czech Academy of Sciences - Na Slovance 2, 182 21 Prague - Czech Republic
Abstract :
A new 1D copper(I) coordination polymer [Cu2(-L)(-I)2]n (1), where L is N,N'-bis(4- itrobenzylidene)butane-1,4-diamine, was synthesized and characterized by CHN, FT-IR, 1H NMR, and single-crystal X-ray analyses. Based on X-ray results, this new compound
crystallizes in a monoclinic system with space group P21/c. The asymmetric unit consists of one copper and one iodine atoms and half of
the Schiff base ligand (L). The flexible Schiff base compound is coordinated to copper(I) ion as a bis-monodentate ligand. The coordination
geometry around the copper(I) ions is distorted trigonal planar. The thermal behavior of 1 was studied using thermogravimetry analysis. Moreover, the nanoparticles of 1 were prepared via the ultrasonic-assisted method and characterized by XRD and SEM analyses
Keywords :
1D copper(I) coordination polymer , Thermogravimetry , Crystal structure , Nanoparticles , Ultrasonic bath
Journal title :
Inorganic Chemistry Research
