Title of article :
Half-Sandwich Ruthenium Complexes of HeterocyclicDithiocarboxylato Ligands
Author/Authors :
El-khateeb, Mohammad Jordan University of Science and Technology - Chemistry Department, JORDAN , Al-Noaimi, Mousa The Hashemite University - Chemistry Department, Jordan , Harb, Mohammad Friedrich-Schiller-Universtat Jena - Institut fur Anorganische Chemie, Germany , Gorlsc, Helmar Friedrich-Schiller-Universtat Jena - Institut fur Anorganische Chemie, Germany , Weigand, Wolfgang Friedrich-Schiller-Universtat Jena - Institut fur Anorganische Chemie, Germany
Abstract :
The heterocyclic-dithiocarboxylato complexes CpRu(PPh3)(k2S,S-S2C-het) [het= 2-C4H3O (1), 2-C4H3S (2), 1-C4H8N (3)] are obtained by the reaction of the ruthenium chloride, CpRu(PPh3)2Cl, with the anions, het-CS2-. The X-ray structure of CpRu(PPh3)(k2S,S-S2C-1-C4H8N) (3) is determined by single crystal X-ray diffraction.
Keywords :
Complexes , Ruthenium , Dithiocarboxylate , Structure , Sulfur , Heterocycles
Journal title :
Jordan Journal of Chemistry
Journal title :
Jordan Journal of Chemistry